Anmol Chemicals is the pioneer manufacturers of Sodium Metabisulfite or Sodium Metabisulphite USP NF BP Ph Eur Reagent FCC Food Grade, Pharmaceutical Excipients Chemicals in India. We offer Halal and Kosher Sodium Metabisulfite or Sodium Metabisulphite made in an ISO9001, ISO22000 (FSSC22000) cGMP and GLP certified facility. Our group has several manufacturing facilities spread across the world, supported by toll manufacturers and representatives in UAE, Europe, Africa, USA, China and has several associated manufacturing facilities spread across India. All the Information on Physics, Chemistry, Applications, Uses and Technology on Manufacture of Sodium Metabisulfite or Sodium Metabisulphite is in these pages. The units have one or more of the certifications like FDA GMP, ISO 9001, ISO 22000, HACCP, REACH, Kosher & Halal Sodium Metabisulfite or Sodium Metabisulphite SDS MSDS of Manufacturers Exporters, CAS Number 7681-57-4
Sodium Metabisulfite or Sodium Metabisulphite SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet1. Product Identification
Product Name & Other Names: Sodium Metabisulfite or Sodium Metabisulphite or Disulfurous acid, Disodium salt or Fertisilo or Pyrosulfurous acid, disodium salt or Sodium disulfite or Disodium pyrosulfite or Sodium pyrosulfite.
CAS No.: 7681-57-4 Sodium Metabisulfite or Sodium Metabisulphite.
EINECS EC Number: 231-673-0
Molecular Weight: 190.11
Chemical Formula: Na2S2O5 (sodium metabisulfite)
Relevant uses and uses advised against (if any): Industrial Manufacturing.2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008Acute toxicity, oral Category 4, H302
Acute toxicity, dermal Category 5, H315
Serious eye damage/eye irritation Category 1, H318Labeling according to GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements
CorrosiveSignal Words: Danger
Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
EUH031: Contact with acids liberates toxic gas.Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash with plenty of water and soap thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Wear protective equipment for hands, eyes, face and respiratory tract.
P270: Do not eat, drink or smoke when using this product.
P301 + P330: IF SWALLOWED: rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313 : If skin irritation occurs: Get medical advice/attention.
P312 : Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container to hazardous or special waste collection point.Classification according to European Directive 67/548/EEC as amended:
Hazard Symbols:
Xn Harmful
C Corrosive.
Risk Phrases:
R22 Harmful if swallowed
R31 Contact with acids liberates toxic gas
R38 Irritating to skin
R41 Risk of serious damage to eyes.3. Composition/Information on Ingredients
Product Name & Other Names: Sodium Metabisulfite or Sodium Metabisulphite or Disulfurous acid, Disodium salt or Fertisilo or Pyrosulfurous acid, disodium salt or Sodium disulfite or Disodium pyrosulfite or Sodium pyrosulfite.
CAS No.: 7681-57-4
EINECS EC Number: 231-673-04. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.5. Fire Fighting Measures
Fire: Not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Do not allow water runoff to enter sewers or waterways.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, acids, alkalis, sodium nitrite, aluminum powder. Avoid moisture, water, ice.8. Exposure Controls/Personal Protection
Airborne Exposure Limits: ACGIH Threshold Limit Value (TLV) 5mg/m3 (TWA)
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face respirator with an acid gas cartridge may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece respirator with an acid gas cartridge may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron, or coveralls, as appropriate, to prevent skin contact. (neoprene, polyvinyl chloride).
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.9. Physical and Chemical Properties
Appearance: White to yellow white crystalline granules.
Odor: Slight odor of sulfur dioxide.
Odor threshold: Not available.
pH: Aqueous solution is acidic.
Relative density: around 1.48
Melting Point: 150C (302F).
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Very soluble in water, insoluble in alcohol.
Viscosity: Not available.10. Stability and Reactivity
Stability: Product is normally stable. Air and moisture sensitive and releases sulfur dioxide slowly at ambient temperatures. Sodium Metabisulfite will decompose on heating to form sodium sulfate. Contact with moisture (water, wet ice, etc.), will release toxic sulfur dioxide gas.
Hazardous Decomposition Products: Oxides of sulfur and sodium may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Water, acids, alkalis, sodium nitrite, oxidizers, aluminum powder.
Conditions to Avoid: Moisture, heat, flames, ignition sources and incompatibles.11. Toxicological Information
LD50 Oral - Rat - 1.540 mg/kg
LD50 Dermal - Rat - > 2.000 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.12. Ecological Information
Toxicity to fish: LC50 - Oncorhynchus mykiss (rainbow trout) - 150 - 220 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 89 mg/l - 24 h
Toxicity to algae: IC50 - Desmodesmus subspicatus (green algae) - 48 mg/l - 72 h
Toxicity to bacteria: Pseudomonas putida - 56 mg/l - 17 h
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Dispose of container of Sodium Metabisulfite and unused contents in accordance with law.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
IMDG/IMO: Not regulated.
IATA/ICAO: Not regulated.15. Regulatory Information
USA:
SARA 311/312: Acute health hazard. See section 2.Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
EUH031: Contact with acids liberates toxic gas.DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable.This Sodium Metabisulfite SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Sodium Metabisulfite or Sodium Metabisulphite USP NF BP Ph Eur Reagent FCC Food Grade manufacturers
Anmol Chemicals
S-8, SARIFA MANSION, 2ND FLANK ROAD, CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 23726950, 23774610, 23723564. FAX: 91-22-23728264e-mail: anmolc@mtnl.net.in
Exports to USA, Canada, UAE, Dubai, South Africa, Tanzania, Kenya, Nigeria, Egypt, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Europe Netherlands, Italy, Spain, Germany, Portugal, France, Malaysia, Indonesia, Thailand, Vietnam, Korea, Japan, etc.
Copyright and Usual Disclaimer is Applicable. 12 January, 2022
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