BHA Butylated hydroxyanisole manufacturers

Anmol Chemicals is the pioneer manufacturers of BHA Butylated hydroxyanisol, Pharmaceutical Excipients Chemicals in India. We offer Halal and Kosher BHA Butylated hydroxyanisol made in an ISO9001, ISO22000 (FSSC22000) cGMP and GLP certified facility. Our group has several manufacturing facilities spread across the world, supported by toll manufacturers and representatives in UAE, Europe, Africa, USA, China and has several associated manufacturing facilities spread across India. All the Information on Physics, Chemistry, Applications, Uses and Technology on Manufacture of BHA Butylated hydroxyanisol is in these pages.

The units have one or more of the certifications like FDA GMP, ISO 9001, ISO 22000, HACCP, REACH, Kosher & Halal

Butylated hydroxyanisole BP USP NF FCC Food Grade Manufacturers Exporters, MSDS

Apart from Butylated hydroxyanisole and Butylated hydroxytoluene, we also offer Tertetiary or Tert Butylhydroquinone the main antioxidants for oils and fats.

Butylated hydroxyanisole is a white to slightly yellow waxy flakes with characteristic odor.
It is freely soluble in alcohol, propylene glycol. It is insoluble in water.

Test ---------------- Result - Specification
Melting Point ------- 62.6C -- 48C to 63C
Residue on ignition - 0.018% - 0.05% max
Arsenic ------------- <1ppm -- 3ppm max
Assay --------------- 99.06% - 98.5% min of C11H16O2

BHA Butylated Hydroxyanisole SDS GHS, MSDS Sheet, Material Safety Data Sheet

Synonyms: "tert-butyl-4-methoxyphenol (2-and 3-mixture)", tert-butyl-p-methoxyphenol, "t-butyl hydroxyanisole", mono-tert-butyl-4-hydroxyanisole.
CAS No.: 25013-16-5
EINECS EC Number: 246-563-8
Molecular Weight: 180.25
Chemical Formula: C11H16O2
Relevant Uses: Industrial use only.
Supplier: As per letterhead above.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral (Category 4)
Skin irritation (Category 2)
Eye irritation (Category 2A)
Carcinogenicity (Category 2)
Specific target organ toxicity - single exposure (Category 3), Respiratory system

Hazard statements:
H302: Harmful if swallowed.
H315: Causes Skin Irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation
H351: Suspected of causing cancer.

Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Use personal protective equipment as required.
P314: Get medical advice/attention if you feel unwell.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Xi Irritant, Xn Harmful,
R22 - Harmful if swallowed
R40 - Limited evidence of a carcinogenic effect
R36/37/38 - Irritating to eyes, respiratory system and skin
For the full text of the H-statements and R-phrases mentioned in this Section, see Section 16.

OSHA Hazards: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
HMIS (Perceived): Health hazard: 2, Flammability: 1, Reactivity: 0, Personal Protection: E
NFPA (Perceived): Health hazard: 2, Fire: 1, Reactivity Hazard: 0, Protective Equip: Goggles, Lab Coat.

Ingredient: Butylated Hydroxyanisole, BHA
CAS No.: 25013-16-5
EINECS EC Number: 246-563-8
Percent: 97 - 100%

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: May be combustible at high temperature..
Flash Points: 156C.
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes.
Fire: Flammable in the presence of open flame.
Explosion: Slightly explosive in presence of heat.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes. Containers may explode on heating

Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Avoid touching the spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Do not contaminate the environment.

Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment.
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Wash hands thoroughly after handling. Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage.

Airborne Exposure Limits: Not established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White to off-white waxy solid.
Odor: It has faint typical odor.
Solubility: It is immiscible in water.
pH: NA
Density: 1.05 g/mL at 20C (68F)
Molecular Weight: 180.2
Molecular Formula: C11H16O2
% Volatiles by volume @ 21C (70F): -
Boiling Point: 264-270°C
Melting Point: 48 - 55 deg C

Stability: Butylated Hydroxyanisole, BHA is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide & Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, reducing agents metals and acids.
Conditions to Avoid: Incompatibles and moisture.
Phenols are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides.
Avoid use of aluminum, copper and brass alloys in storage and process equipment.
Heat is generated by the acid-base reaction between phenols and bases.
Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature), these reactions generate heat.
Phenols are nitrated very rapidly, even by dilute nitric acid.
Nitrated phenols often explode when heated. Many of them form metal salts that tend toward detonation by rather mild shock.
Segregate from oleum, nitric acid and chlorosulfonic acid.

Toxicity data
ORL-RAT LD50 > 2000 mg kg-1
ORL-MAM LD50 1100 mg kg-1
Carcinogenic Effects: Classified 2B (Possible for human.) by IARC. Classified 2 (Some evidence.) by NTP.
Mutagenic Effects: Mutagenic for bacteria and/or yeast. May cause damage to the following organs: blood, liver, upper respiratory tract, skin.
Teratogenic Effects: Teratogenic effects have occurred in experimental animals.
Developmental Toxicity: Adverse reproductive effects have occurred in experimental animals.
May affect genetic material (mutagenic). May cause adverse reproductive effects based on animal test data. May cause cancer.

Environmental Fate: Not available.
Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

US DOT Classification:
Not Regulated
Canada TDG Classification:
Not Regulated
IATA:
Not Regulated

USA:
OSHA Hazards: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
SARA 302 Components : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components: No chemicals are reportable under Section 313.
SARA 311/312 Hazards
Component CAS # 25013-16-5.
Fire Hazard: No; Reactivity Hazard: No; Pressure Hazard: No; Immediate Health Hazard: Acute
Chronic Health Hazard: Delayed.
TSCA : CAS# 25013-16-5 is listed on the TSCA Inventory.
Health & Safety Reporting List : None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules : None of the chemicals in this product are under a Chemical Test Rule.
Section 12b: None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs : None of the chemicals in this material have an RQ.
Massachusetts Right To Know Components: Listed
Pennsylvania Right To Know Components: Listed
New Jersey Right To Know Components: Listed
California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: BHA
California prop. 65 (no significant risk level): BHA: 4 mg/day (value)
California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: BHA
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

WGK (Water Danger/Protection): CAS# 25013-16-5: No information available.

Canada - DSL/NDSL: CAS# 7447-39-4 is listed on Canada's DSL List.
Canada - WHMIS: CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
Canadian Ingredient Disclosure List: CAS# 25013-16-5 is listed on the Canadian Ingredient Disclosure List.

EINECS EC Number: 246-563-8
H302 = Harmful if swallowed.
H315 = Causes Skin Irritation.
H319 = Causes serious eye irritation.
H335 = May cause respiratory irritation
H351 = Suspected of causing cancer.
Xi = Irritant
Xn = Harmful,
R22 = Harmful if swallowed
R40 = Limited evidence of a carcinogenic effect
R36/37/38 = Irritating to eyes, respiratory system and skin
Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 29 Do not empty into drains. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately. S 61 Avoid release to the environment.

Disclaimer:
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Our company provides this BHA Butylated Hydroxyanisole SDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Anmol Chemicals
S-8, SARIFA MANSION, 2ND FLANK ROAD, CHINCHBUNDER, MUMBAI 400009, INDIA
TEL: (OFFICE) 91-22-23770100, 23726950, 23774610, 23723564. FAX: 91-22-23728264

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